You can use the envelope templates in Pages to print standard-sized envelopes.
Go to the Pages app
on your iPad.
In the document manager, tap Choose a Template.
Scroll down to the Envelopes section, then tap an envelope template.
Tap the placeholder text in the recipient address, then type your contact’s address.
You can add or delete lines as needed.
Double-tap text in the return address, then type your address.
The return address is a text box. Drag the handles if you want to resize it.
Tap the document’s name in the toolbar, then tap Print.
If no printer is selected, tap Printer.
Your device automatically searches for any nearby AirPrint printers. Tap a printer in the list to select it.
Tap Print.