RAID configurations that aren't supported include Microsoft Windows' built-in software RAID, hardware RAID cards (such as Mac Pro RAID and Xserve RAID cards).
Learn More
To partition your disk and install Windows using Boot Camp Assistant, the disk must be a single partition which is formatted as a Mac OS X Extended (Journaled) volume. If you have already partitioned your disk using Disk Utility or another utility, you cannot use Boot Camp Assistant until you restore your disk to a single-partition Mac OS X volume.
Also, Boot Camp Assistant works only with internal disks. You cannot use Boot Camp Assistant to partition and install Windows on an external disk.